Hi @blissy, welcome to the community!
So when you see that error, it’s because your CSV has more than one column. Make sure it’s only an email address (one per line), with no additional columns (like First Name, or other data).
If you think your CSV only has email addresses and no other columns and you are still getting an error, it might mean that your CSV may have empty columns on it. Try deleting any columns (even if it appears empty) in your spreadsheet then saving it again as CSV. Another way to check is to open the CSV with a text editor and see how many “commas” are in there. There should be at most one comma, or none at all.
Hope that helps!